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Microplastics are found floating on natural waters. Sunlight-driven photochemistry can dissolve buoyant microplastics, producing dissolved organic carbon (DOC). We hypothesized that plastic dissolution would increase linearly with increasing surface area (SA)-to-volume (V) ratio as plastics decrease in size. To test this, samples of expanded polystyrene (EPS) and polypropylene (PP) spanning a range of sizes were irradiated while floating on water in a solar simulator. A linear relationship between SA:V and DOC accumulation rate was significant for EPS (p < 0.0001) and PP (p = 0.0086), suggesting SAcontrolled reactions. However, a power relationship with an exponent of approximately 0.5 between PP dissolution and SA:V provided a significantly better fit, suggesting that non-SAcontrolled processes may limit PP photodissolution. Using these relationships, it was estimated that macroplastics ∼10 cm should take ∼250 to ∼8000 years to photochemically dissolve. However, estimated lifetimes are shorter for smaller plastics, with 1 mm EPS beads and 100 nm PP nanoplastics estimated to have lifetimes of 5.3 years and 3 to 196 days, respectively, with the range in lifetimes for PP dependent upon whether linear or power fits are applied 

Abstract The Mississippi River is a vital economic corridor used for generating hydroelectric power, transporting agricultural products, and municipal and industrial water use. Communities, industries, and infrastructure along the Mississippi River face an uncertain future as it grows more susceptible to climate extremes. A key challenge is determining whether Mississippi river discharge will increase or decrease during the 21st century. Because the 20th century record is limited in time, paleoclimate data and model simulations provide enhanced understanding of the basin's hydroclimate response to external forcing. Here, we investigate how anthropogenic forcing in the 20th century shifts the statistics of river discharge compared to a Last Millennium (LM) baseline using simulations from the Community Earth System Model Last Millennium Ensemble. We present evidence that the 20th century exhibits wetter conditions (i.e., increased river discharge) over the basin compared to the pre‐industrial, and that land use/land cover changes have a significant control on the hydroclimatic response. Conversely, while precipitation is projected to increase in the 21st century, the basin is generally drier (i.e., decreased river discharge) compared to the 20th century. Overall, we find that changes in greenhouse gases contribute to a lower risk of extreme discharge and flooding in the basin during the 20th century, while land use changes contribute to increased risk of flooding. The additional climate information afforded by the LM simulations offers an improved understanding of what drove extreme flooding events in the past, which can help inform the development of future regional flood mitigation strategies. 

The role of high latitude lakes in storing and processing terrestrial organic carbon export is not well understood. We analyzed a 2.7-meter (m) -long sedimentary record from Eight Mile Lake that extends back 15,700 years to evaluate connections between productivity, organic carbon accumulation and late Quaternary environmental change in central Alaska. We analyzed macrofossil radiocarbon, alongside physical and biogeochemical properties. This dataset includes data from 12 sediment cores collected across Eight Mile Lake. These cores span time frames of 1000 - 15,700 years. This dataset includes bulk physical data, organic matter abundance, biogenic silica abundance, particle size, geochronological information, magnetic susceptibility data and hyperspectral imagery. 

Abstract The Mississippi River basin drains nearly one-half of the contiguous United States, and its rivers serve as economic corridors that facilitate trade and transportation. Flooding remains a perennial hazard on the major tributaries of the Mississippi River basin, and reducing the economic and humanitarian consequences of these events depends on improving their seasonal predictability. Here, we use climate reanalysis and river gauge data to document the evolution of floods on the Missouri and Ohio Rivers—the two largest tributaries of the Mississippi River—and how they are influenced by major modes of climate variability centered in the Pacific and Atlantic Oceans. We show that the largest floods on these tributaries are preceded by the advection and convergence of moisture from the Gulf of Mexico following distinct atmospheric mechanisms, where Missouri River floods are associated with heavy spring and summer precipitation events delivered by the Great Plains low-level jet, whereas Ohio River floods are associated with frontal precipitation events in winter when the North Atlantic subtropical high is anomalously strong. Further, we demonstrate that the El Niño–Southern Oscillation can serve as a precursor for floods on these rivers by mediating antecedent soil moisture, with Missouri River floods often preceded by a warm eastern tropical Pacific (El Niño) and Ohio River floods often preceded by a cool eastern tropical Pacific (La Niña) in the months leading up peak discharge. We also use recent floods in 2019 and 2021 to demonstrate how linking flood hazard to sea surface temperature anomalies holds potential to improve seasonal predictability of hydrologic extremes on these rivers. 

Black carbon is a paleofire proxy that has been measured from glacial ice, snow, soils and lake sediments, though relatively few comparisons have been made with other fire indicators in sedimentary geoarchives. Microscopic charcoal, quantified from palynological microscope slides and macroscopic charcoal, quantified from wet-sieved deposits, are the most commonly applied methods for paleofire interpretation of Quaternary sediments. This research explores the down-profile patterns across three paleofire proxies (refractory black carbon, microscopic and macroscopic charcoal) and potential paleofire interpretations from a sediment core dating to the last centuries from Speke Gulf, Lake Victoria, and a young soil profile from a kopje located in the surrounding watershed in Serengeti National Park, Tanzania. The results of three paleofire metrics show similar trends within each site, with a positive trend across all metrics and increasing variability with increased measurement values (heteroscedastic). Notably, refractory black carbon (rBC) concentrations are two orders of magnitude higher in lake sediment samples compared to soil samples. rBC is positively correlated with both microscopic and macroscopic charcoal values and the overall profile patterns down the sediment core are similar, with the exception of the rBC increases from 2.5 to 0 cm depth that may result from increased fossil fuel combustion. The Speke Gulf rBC measurements are in an intermediate range between those published from glacial ice and other lake sediments. New rBC records from different ecosystems and temporal scales will provide paleofire insights and potential to interpret source areas and depositional patterns. The exploration of soil archives offers the potential to exploit semi-arid ecosystems and archaeological sites that have no nearby traditional paleoenvironmental study site targets. 

Plastic contamination of the environment is a global problem whose magnitude justifies the consideration of plastics as emergent geomaterials with chemistries not previously seen in Earth’s history. At the elemental level, plastics are predominantly carbon. The comparison of plastic stocks and fluxes to those of carbon reveals that the quantities of plastics present in some ecosystems rival the quantity of natural organic carbon and suggests that geochemists should now consider plastics in their analyses. Acknowledging plastics as geomaterials and adopting geochemical insights and methods can expedite our understanding of plastics in the Earth system. Plastics also can be used as global-scale tracers to advance Earth system science.